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This study aims to focus on the main materials used in consolidation processes of illuminated paper manuscripts and leather binding.

For each material, chemical structure, chemical composition, molecular formula, solubility, advantages, disadvantages and its role in treatment process are presented.

This study concluded that carboxy methyl cellulose, hydroxy propyl cellulose, methyl cellulose, cellulose acetate, nanocrystalline cellulose, funori, sturgeon glue, poly vinyl alcohol, chitosan, chitosan nanoparticles (NPs), gelatin, aquazol, paraloid B72 and hydroxyapatite NPs were the most common and important materials used for the consolidation of illuminated paper manuscripts. For the leather bindings, hydroxy propyl cellulose, polyethylene glycol, oligomeric melamine-formaldehyde resin, acrylic wax SC6000, pliantex, paraloid B67 and B72, silicone oil and collagen NPs are the most consolidants used.

Illuminated paper manuscripts with leather binding are considered one of the most important objects in libraries, museums and storehouses. The uncontrolled conditions and other deterioration factors inside the libraries and storehouses lead to degradation of these artifacts. The brittleness, fragility and weakness are considered the most common deterioration aspects of illuminated paper manuscripts and leather binding. Therefore, the consolidation process became vital and important to solve this problem. This study presents the main materials used for consolidation process of illuminated paper manuscripts and leather bindings.

This study aims to evaluate the state of preservation of one of the most famous manuscripts dated back to the 15th century using some analytical techniques to identify the manuscript components, explain its deterioration mechanisms and produce some solutions for conservation processes in future studies.

The analytical techniques used were visual assessment, digital microscope, scanning electron microscope (SEM) with EDX, pH measurement, attenuated total reflection – Fourier transform infrared spectroscopy (ATR/FTIR) and cellulose crystallinity.

Stains, missed parts and scratching were the most common aspects of deterioration. Some insects were observed by digital microscope. The SEM showed that linen fibers and goat skin were used to manufacture paper sheets and leather binding. Energy dispersive X-ray analysis proved that niobium and tantalum were added during the manufacture of paper sheets. Carbon black ink was the main writing material. The other pigments used were cinnabar in red ink, gold color from brass and blue color from lapis lazuli. FTIR analysis proved that some chemical changes were noticed. Low crystallinity of the historical paper was obtained. There was a reduction in the pH value of the historical bookbinding.

The importance of the analytical techniques used to detect the main components, forms and mechanism of deterioration of the studied manuscript. The elements of niobium and tantalum were added to paper sheets, which protected them from deterioration. The insects such as house flies and Sitophilus granarius were found in the manuscripts.

This study aims to evaluate the efficiency of using some polymers at different concentrations in the consolidation of vegetable-tanned leather artifacts.

New vegetable-tanned leather samples were prepared. The consolidants used were polyacrylamide (PAM) and polymethyl methacrylate/hydroxyethyl methacrylate (MMA-HEMA). Accelerated heat aging was applied to the untreated and treated samples. Analytical techniques used were Fourier transform infrared spectroscopy (FTIR), digital microscope, scanning electron microscope (SEM), change of color and mechanical properties.

The characteristic FTIR bands showed the effect of accelerated heat aging on the molecular structure of the studied samples, but treated and aged treated samples used were better than aged untreated samples. Microscopic investigations (digital and SEM), and mechanical properties proved that 2% was the best concentration for polymers used. The change in the total color difference of the treated and aged treated samples was limited.

This study presents the important results obtained from PAM and poly(MMA-HEMA) used for the consolidation of vegetable-tanned leather artifacts. The best results of the studied polymers can be applied directly to protect historical vegetable-tanned leathers.

This study aims to use whiteness (WI) and yellowness indices (YI) that were calculated from the International Commission on Illumination (CIE) color parameter to evaluate the efficiency of some triazole fungicides [propiconazole (C₁₅H₁₇Cl₂N₃O₂) and tebuconazole (C₁₆H₂₂ClN₃O)] to protect wooden artifacts from fungal deterioration.

Archeological wooden samples were collected from some historical Islamic buildings in Cairo, Egypt. Three species of fungi were identified in previous work. Propiconazole and tebuconazole with different concentrations treated the infected wooden samples aged for different periods. WI and YI of studied samples were measured using UV spectrophotometer. Calibration and uncertainty estimation accompanied by color measurement were studied.

Studying the uncertainty sources of diffuse reflection of the standard white tiles revealed that the uncertainty of calibration for both the spectrophotometer and white tiles had the highest contribution. The treated samples with tebuconazole and propiconazole fungicides gave good resistance against fungal deterioration at 0.50% for WI and YI.

This study presents the importance of colorimetry in the conservation field because they are considered one of the most important criteria to evaluate conservation materials. From color measurements and their uncertainties, it became clear that triazole fungicides have good efficiency in the protection of wooden artifacts from fungal deterioration. The value of this study is that propiconazole and tebuconazole fungicides at 0.50% can be applied to archaeological wood that is endangered to improper conditions, especially in the case of high levels of relative humidity.

This paper aims to present the components' characterization and condition assessment of an important deteriorated Mamluk-illuminated paper manuscript housed in Al-Azhar Library, Egypt.

Different analytical techniques used in this study were the portable digital optical microscope, stereomicroscope, scanning electron microscope with EDX (SEM.EDX), portable X-ray fluorescence (pXRF), X-ray diffraction (XRD), pH measurement and Fourier transform infrared spectroscopy (FTIR).

The results obtained by different microscopes showed that the gilding in the surface of illuminated paper sheets was performed with gold leaves. Additionally, these microscopes revealed that the illuminated paper manuscript has different aspects of deterioration such as adhered dirt, staining, some micro-cracks, cracks and detachment of some parts in some illuminated areas. The results of elemental analysis by EDX, portable XRF and XRD analysis showed that the orange red pigment is red lead (Pb₃O₄), blue pigment is azurite (2CuCo₃.Cu (OH)₂), and the gold layer is has consisted of brass alloy (Cu-Zn) with a small amount of gold element (Au). The pH measurement stated that the historical paper in the acidity level. The ATR-FTIR analysis also revealed the oxidation of cellulose. Moreover, it was found from ATR-FTIR that Arabic gum was used as a binder for the pigments.

This study presents the important results of analytical methods used for condition assessment and identification of the components of an important Mamluk-illuminated paper manuscript, where these results referred that the studied paper manuscript had different aspects of deterioration. The conservation steps either conservation treatment or preventive conservation are urgently needed in future studies.