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A highly selective cyanide phenoxazine-based fluorescence chemosensor POH was created to detect cyanide (CN) ions.

A malonitrile was added to a phenoxazine fluorophore to make this widely available chemosensor. By fluorescence spectroscopy, the sensor POH showed turn-off fluorescence emission for CN with 2:1 binding stoichiometry in CH₃CN/H₂O (90:10 v/v) medium.

The detection limits for CN were 9.8 × 10⁻⁹ M, which were much lower than WHO standards. NMR and FT-IR investigations backed up the suggested sensor POH mechanism.

The detection CN method should be applicable in a number of situations, where the CN anion for fresh water and drinking water has to be quickly and accurately analyzed.